Chemistry in Nonaqueous Ionizing Solvents: Volume II - Part 1 investigates the chemical and physico-chemical properties of substances dissolved or suspended in non-aqueous ionizing solvents (also known as water-like solvents). This volume is concerned with chemistry in anhydrous hydrogen cyanide and with inorganic chemistry in liquid hydrogen fluoride. This book is comprised of 35 chapters that cover topics ranging from commercial preparation of hydrogen fluoride to laboratory preparation of pure hydrogen fluoride as well as deuterium and tritium fluorides. Experimental techniques and the apparatus used in investigations of liquid hydrogen fluoride are also described. Subsequent chapters explore health risks and first aid with respect to handling hydrogen fluoride; physical properties of the pure solvent; inorganic solvates; solubilities and reactions of inorganic compounds; and acids and bases and their reactions with each other. The last two chapters are devoted to fluorides of the lanthanides and actinides in hydrogen fluoride. This monograph will be of interest to chemists.

Part 1 Anorganische Chemie in flüssigem Cyanwasserstoff 1. Das Lösungsmittel flüssiger Cyanwasserstoff 1.1. Physikalische Daten des reinen Solvens 1.2. Struktur des Solvens HCN 2. Das Verhalten anorganischer Verbindungen im Lösungsmittel Cyanwasserstoff 2.1. Additionsverbindungen mit Cyanwasserstoff (Solvate) 2.2. Die Löslichkeit von anorganischen Substanzen und Salzen organischer Ionen in flüssigem Cyanwasserstoff 2.3. Lösungszustand 2.4. Das Solvosystem des flüssigen Cyanwasserstoffs 2.5. Das Verhalten von "Säure-Basen" - Indikatoren in flüssigem wasserfreiem Cyanwasserstoff 2.6. Neutralisationenanaloge Reaktionen in flüssigem Cyanwasserstoff 2.7. Solvolyse-Reaktionen in wasserfreiem Cyanwasserstoff 2.8. Die Erscheinung der Amphoteric in flüssigem Cyanwasserstoff 2.9. Weitere Reaktionen in flüssigem Cyanwasserstoff 3. Das Verhalten organischer Verbindungen im Lösungsmittel Cyanwasserstoff 3.1. Additionsverbindungen mit Cyanwasserstoff (Solvate) 3.2. Die Löslichkeit von organischen Verbindungen in wasserfreiem Cyanwasserstoff 3.3. Lösungszustand 3.4. Solvolysereaktionen organischer Verbindungen in wasserfreiem Cyanwasserstoff 3.5. Bemerkung über weitere Reaktionen organischer Verbindungen in und mit Cyanwasserstoff 4. Literaturverzeichnis SachwortverzeichnisPart 2 Inorganic Chemistry in Liquid Hydrogen Fluoride 1. Commercial Preparation of Hydrogen Fluoride 2. Laboratory Preparation of Pure Hydrogen Fluoride 3. Laboratory Preparation of Deuterium and Tritium Fluorides 4. Preparation of 18 F-Labeled Hydrogen Fluoride 5. Experimental Techniques 5.1. Constructional Materials 5.2. Apparatus 6. Health Risks and First Aid 7. Physical Properties of the Pure Solvent 8. Structure of the Solvent 8.1. Solid Hydrogen Fluoride 8.2. Gaseous Hydrogen Fluoride 8.3. Liquid Hydrogen Fluoride 9. Inorganic Solvates 10. Solubilities and Reactions of Inorganic Compounds 10.1. Introductory Remarks 10.2. Elements 10.3. Halides 10.4. Oxides, Hydroxides, and Salts of Oxyacids 10.5. Azides, Cyanides and Sulphides 10.6. Miscellaneous 11. Acids and Bases 11.1. Formal Definitions 11.2. Quantitative Measurements 11.3. Basic Solutes 11.4. Acidic Solutes 11.5. Neutral Solutes 12. Acid-Base Reactions 12.1. Conductimetric and Tensimetric Titrations 12.2. Preparative Reactions 12.3. Solvolysis of Fluoro Anions 12.4. Amphoteric Behavior 13. Redox Reactions 13.1. Electrode Potentials 13.2. Polarography 13.3. Electrolytic Reactions 13.4. Chemical Agents 14. Complexions 14.1. Fluoro Anions 14.2. Complex Cations 15. H2O-HF System 15.1. Hydrofluoric Acid 15.2. Wet Hydrogen Fluoride 15.3. Hammett Acidity Function 15.4. Phase Diagram 15.5. Vapor Pressures and Boiling Points 15.6. Density Measurements 15.7. Conductivity Measurements 15.8. Infrared Spectroscopy 15.9. Nuclear Magnetic Resonance Spectroscopy 15.10. Solvent Extraction 16. SO2-HF System 17. Alkali Metal Fluorides in HF 17.1. Lithium Fluoride 17.2. Sodium Fluoride 17.3. Potassium Fluoride 17.4. Rubidium Fluoride 17.5. Cesium Fluoride 18. Ammonium and Substituted Ammonium Fluorides in HF 18.1. Ammonium Fluoride 18.2. Substituted Ammonium Fluorides 19. Group II Metal Fluorides in HF 19.1. Beryllium Fluoride 19.2. Magnesium Fluoride 19.3. Calcium Fluoride 19.4. Strontium Fluoride 19.5. Barium Fluoride 20. Group III Fluorides in HF 20.1. Boron Trifluoride 20.2. Aluminum Trifluoride 20.3. Gallium Fluorides 20.4. Indium Trifluoride 20.5. Thallium Fluorides 21. Group IV Fluorides in HF 21.1. Carbon Fluorides 21.2. Silicon Tetrafluoride 21.3. Germanium Tetrafluoride 21.4. Tin Fluorides 21.5. Lead Fluorides 22. Group V Fluorides in HF 22.1. Nitrogen Fluorides and Oxyfluorides 22.2. Phosphorus Fluorides 22.3. Arsenic Fluorides 22.4. Antimony Fluorides 22.5. Bismuth(IH) Fluoride 23. Group VI Fluorides in HF 23.1. Oxygen Difluoride 23.2. Sulphur Fluorides and Oxyfluorides 23.3. Selenium(IV) Fluoride 23.4. Tellurium (IV) Fluoride 24. Halogen Fluorides in HF 24.1. Chlorine Fluoride 24.2. Bromine Fluorides 24.3. Iodine Fluorides and Oxyfluorides 25. Noble Gas Fluorides in HF 25.1. Krypton(II) Fluoride 25.2. Xenon Fluorides 26. Titanium, Zirconium and Hafnium Fluorides in HF 26.1. Titanium(IV) 26.2. Zirconium(IV) 26.3. Hafnium(IV) 27. Vanadium, Niobium and Tantalum Fluorides in HF 27.1. Vanadium(IV) 27.2. Vanadium(V) 27.3. Niobium(V) 27.4. Tantalum(V) 28. Chromium, Molybdenum and Tungsten Fluorides in HF 28.1. Chromium(III) 28.2. Chromium(VI) 28.3. Molybdenum(V) 28.4. Molybdenum(VI) 28.5. Tungsten(VI) 29. Manganese and Rhenium Fluorides in HF 29.1. Manganese(III) 29.2. Manganese(VII) 29.3. Rhenium(VI) 29.4. Rhenium(VII) 30. Iron, Cobalt and Nickel Fluorides in HF 30.1. Iron 30.2. Cobalt 30.3. Nickel(II) 30.4. Nickel(III) 30.5. Nickel(IV) 31. Palladium, Osmium, and Platinum Fluorides in HF 31.1. Palladium(IV) 31.2. Osmium(VI) 31.3. Platinum(II) 31.4. Platinum(IV) 32. Copper and Silver Fluorides in HF 32.1. Copper(II) 32.2. Silver(I) 32.3. Silver (II) 33. Zinc, Cadmium and Mercury Fluorides in HF 33.1. Zinc(II), Cadmium(II) and Mercury(I) 33.2. Mercury(II) 34. Fluorides of the Lanthanides in HF 35. Fluorides of the Actinides in HF 35.1. Thorium(IV) 35.2. Uranium(IV) 35.3. Uranium(V) 35.4. Uranium(VI) 35.5. Neptunium(IV) and Neptunium(V) 35.6. Plutonium(VI)ReferencesIndex